Search In this Thesis
   Search In this Thesis  
العنوان
EFFECT OF SUBSTITUTION OF DIFFERENT VALENT IONS ON ELECTRICAL AND MAGNETIC PROPERTIES OF Li-Zn FERRITE
المؤلف
RAGAB ABDUR RASHEED AGAMI,WALEED
هيئة الاعداد
باحث / WALEED RAGAB ABDUR RASHEED AGAMI
مشرف / Ali Ibrahim Ali Eatah
مشرف / Adel Abd El-Sattar
مشرف / Hesham El-Sayed
الموضوع
Factors Influencing the Cation Distribution in<br> Spinel Ferrites<br>.
تاريخ النشر
2009
عدد الصفحات
212.p؛
اللغة
الإنجليزية
الدرجة
الدكتوراه
التخصص
فيزياء المادة المكثفة
تاريخ الإجازة
1/1/2009
مكان الإجازة
جامعة عين شمس - كلية العلوم - Physics
الفهرس
Only 14 pages are availabe for public view

from 228

from 228

Abstract

In this study, the physical, magnetic and electrical properties of four systems of mixed ferrites are investigated. The chemical compositions of these systems are:
1) Li0.3-0.5xZn0.4CaxFe2.3-0.5xO4 (x=0.0, 0.01, 0.02, 0.03 and 0.05), referred as (Ca-system).
2) Li0.3Zn0.4BixFe2.3-xO4 (x= 0.0, 0.02, 0.05 and 0.075), referred as (Bi-system).
3) Li0.3+0.5xZn0.4ZrxFe2.3-1.5xO4 (x=0.0, 0.01, 0.02, 0.03 and 0.05), referred as (Zr-system).
4) Li0.3+xZn0.4NbxFe2.3-2xO4 (x=0.0, 0.01, 0.02, 0.03 and 0.05), referred as (Nb-system).
According to the obtained results, the conclusions could be divided into general and special conclusions:
I- General conclusions:
1- All the investigated samples are formed in a single phase.
2- All systems improved the magnetization, the coercivity and the squareness (except Nb-system) which are important properties in memory applications.
3- All studied systems improved the initial permeability and the homogeneity (except Ca-system) which are important properties in transformer core applications.
4- The thermoelectric power α measurements indicated that the majority of charge carriers are electrons for all systems.
5- The temperature dependence of resistivity and thermoelectric power showed that the electron hopping mechanism is the appropriate one to account for the conduction mechanism in the ferrimagnetic region.
II- Special conclusions:
For Ca-system:
It has the maximum improvement in coercivity (55%) and squareness (160%) while it decreased both the homogeneity and initial permeability. It decreased also the resistivity (except for x=0.05) and consequently increased the dielectric constant.
For Bi-system:
It has the maximum improvement of initial permeability (82%) and homogeneity (4 times). It increased the resistivity and decreased Curie temperature.
For Zr-system:
It has the maximum improvement in magnetization (14.1%) and resistivity. It has the minimum loss (25% of unsubstituted sample).
For Nb-system:
It has the minimum porosity (4.5%). It decreased the coercivity, the squareness and Curie temperature. It has the maximum improvement of the dielectric constant (75%).
Based on the above statements, it is concluded that the substitution with different valent ions generally improves the magnetic and electrical properties of Li-Zn ferrite which are promising results for different applications.