الفهرس | Only 14 pages are availabe for public view |
Abstract In this study, the physical, magnetic and electrical properties of four systems of mixed ferrites are investigated. The chemical compositions of these systems are: 1) Li0.3-0.5xZn0.4CaxFe2.3-0.5xO4 (x=0.0, 0.01, 0.02, 0.03 and 0.05), referred as (Ca-system). 2) Li0.3Zn0.4BixFe2.3-xO4 (x= 0.0, 0.02, 0.05 and 0.075), referred as (Bi-system). 3) Li0.3+0.5xZn0.4ZrxFe2.3-1.5xO4 (x=0.0, 0.01, 0.02, 0.03 and 0.05), referred as (Zr-system). 4) Li0.3+xZn0.4NbxFe2.3-2xO4 (x=0.0, 0.01, 0.02, 0.03 and 0.05), referred as (Nb-system). According to the obtained results, the conclusions could be divided into general and special conclusions: I- General conclusions: 1- All the investigated samples are formed in a single phase. 2- All systems improved the magnetization, the coercivity and the squareness (except Nb-system) which are important properties in memory applications. 3- All studied systems improved the initial permeability and the homogeneity (except Ca-system) which are important properties in transformer core applications. 4- The thermoelectric power α measurements indicated that the majority of charge carriers are electrons for all systems. 5- The temperature dependence of resistivity and thermoelectric power showed that the electron hopping mechanism is the appropriate one to account for the conduction mechanism in the ferrimagnetic region. II- Special conclusions: For Ca-system: It has the maximum improvement in coercivity (55%) and squareness (160%) while it decreased both the homogeneity and initial permeability. It decreased also the resistivity (except for x=0.05) and consequently increased the dielectric constant. For Bi-system: It has the maximum improvement of initial permeability (82%) and homogeneity (4 times). It increased the resistivity and decreased Curie temperature. For Zr-system: It has the maximum improvement in magnetization (14.1%) and resistivity. It has the minimum loss (25% of unsubstituted sample). For Nb-system: It has the minimum porosity (4.5%). It decreased the coercivity, the squareness and Curie temperature. It has the maximum improvement of the dielectric constant (75%). Based on the above statements, it is concluded that the substitution with different valent ions generally improves the magnetic and electrical properties of Li-Zn ferrite which are promising results for different applications. |