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Abstract During the late 1970’s, technology concerned with new concepts and techniques in large-scale fermentation was undergoing rapid development and, as a consequence, new and exciting possibilities for the application of microorganisms in the manufacturing industries emerged. The use of microorganisms in the manufacture of plastics and synthetic fibres was therefore considered by the petrochemical industries to be one possible means of alleviating some of their problems. Although, at present, no large-tonnage plastics or their polymerization monomers are produced commercially by microorganisms, a considerable amount of original research has been undertaken in this area. The use of microorganisms in the manufacture of plastics and synthetic fibres may be divided into two categories. The first involves the microbial biosynthesis of polymers which, by virtue of their chemical and physical properties, resemble plastics derived by other means and so may be further processed, by similar methods, into moulded items, films or fibres. The second employs microorganisms as biocatalysts in the formation of chemical intermediates or monomers which may then be polymerized and processed by traditional chemical routes to form plastics or synthetic fibres. Several microbial polymers, often referred to as biopolymers, are known to be produced by microorganisms, for example pullulan, dextran, xanthan, gellan gum, Zanflo and polytran. |