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العنوان
STUDIES ON 4-THIAZOUDINONES
المؤلف
MOHAMED;SAAD RAMADAN
هيئة الاعداد
باحث / شعد رمضان محمد
مشرف / M.T. Omar
مشرف / A.A.EL-Khamery
مشرف / A. H. Youssef
تاريخ النشر
1991
عدد الصفحات
151 ص
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
الكيمياء
تاريخ الإجازة
1/1/1991
مكان الإجازة
جامعة عين شمس - كلية العلوم - الكيمياء
الفهرس
Only 14 pages are availabe for public view

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from 151

Abstract

CHEMISTRY OF 4-0XO-THIAZOLIDINES
4-oxo-thiazolidines ( 2) are derivatives of thiazolidine
(1) with a carbonyl group at position-4.
-, --NH
I . sJo
(1)
The substituents in the 4-oxo-thiazolidine ring in the 2,3
and 5-positions may be varied to give different derivatives,
but the greatest difference in structure and properties is exerted
by the group attached to the carbon atom in the 2-
position, to give 2,4- dioxo-thiazolidine (3), 2-thioxo-4-oxothiazolidine
(4), and 2-imino-4-oxo-thiazolidine (5), ring sys-
-:.ems.
O=C--NH
S~C=O
(3)
SYNTHESIS OF 4-oxo-THIAZOL\DINES
1-from dithiocarbamates
S=C---llNH
(4)
HN=C--NH
S~C=O
(5)
Dithiocarbamates, formed by the reaction of
ammon1. .a 1-3
pr1.. mary arru. nes 1-3 or arru. no ac1’.d s 4,5 w1. .t h car b on d1’ .su l p h1’ .de in
the presence of a base, reacted with a-haloalkanoic acids to
give the respective 2-thioxo-4-oxo-thiazolidines (